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Activated Carbon In Filtration

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    Posted: October 23 2003 at 1:53pm

After a conversation with Mark P last night regarding activated carbon, I thought that I would offer some explanation and maybe clarification, IME, on the subject.

"Activated Carbon" is an organic that has been particulated and fractured. There are many forms of activated carbon, and some work better for targeted contaminants than others. How is it activated? The particulates are rapidly heated then rapidly cooled which caused small fractures in the particulate which increases surface area.

Activated carbon works on ADsorbtion. Matter and contaminants are trapped on the and in the surface area. For instance, activated carbon quickly and effectively removes chlorine from water.  The presence of organic matter in water can cause color, taste, and odor complaints. Activated carbon adsorbs organic matter in its extensive network of pores. The adsorption process takes time.

Synthetic organic chemicals (SOC) include all man-made organics, some of which are volatile organic compounds (VOC). Activated carbon can substantially reduce many VOCs such as benzene, trichlorethane, and carbon tetrachloride. Activated carbon also removes SOCs such as Alachlor, EDB, and toluene as well as a host of other metal contaminants, etc.

Activated carbon beds compact with use so they may need occasional backwashing. In general, however, backwash carbon when the pressure difference between the filter inlet and outlet increases by 5 - 10 psi (34 to 68 kPa) from the beginning of the filtration cycle. When operating a carbon filter on turbid water supplies, remove suspended particles with a pre-filter before treating it with activated carbon.

Over a period of several months to years, the carbon's adsorption capacity diminishes, which means that the pores of the media become impacted and cannot contain any more contaminants. The exhausted carbon bed should be replaced with fresh carbon.

  Hope that this helps someone somehow.



Edited by Carl
In Syracuse

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jfinch View Drop Down
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Post Options Post Options   Thanks (0) Thanks(0)   Quote jfinch Quote  Post ReplyReply Direct Link To This Post Posted: October 23 2003 at 4:37pm

Very good explaination Carl  (Oh Culligan man...)

We've had a few good discussions here regarding GAC, a quick search should bring them up.  Dechlorination using GAC is interesting (probably only to me ).  It is one of very few (actually the only one I can think of off the top of my head) siturations that GAC participates in a chemical reaction.  Not adsorbtion!  There are many ways to express the reaction but this one summarizes it.

OCl-        +          C          =          CO2       +         Cl-
chlorine          Activated              Carbon           Chloride Ion
(as chlorate)    Carbon                Dioxide           (harmless)

 

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Post Options Post Options   Thanks (0) Thanks(0)   Quote rfoote Quote  Post ReplyReply Direct Link To This Post Posted: October 23 2003 at 6:12pm
Wow, I think Jon's found a friend!

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Post Options Post Options   Thanks (0) Thanks(0)   Quote SSpargur Quote  Post ReplyReply Direct Link To This Post Posted: October 23 2003 at 7:28pm

I enjoy reading the scientific garble, don't know what it means but I enjoy it none-the-less.

Sean Spargur
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Post Options Post Options   Thanks (0) Thanks(0)   Quote Carl Quote  Post ReplyReply Direct Link To This Post Posted: October 23 2003 at 8:28pm

LOL... Thanks for the scientific input JF! I did know that GAC actually reacted to/with chlorine, but wanted to dig a bit into the myth that it was very short lived as filtrate. It is quite effective as a media and has significant longevity. Adsorbtion is probably it's largest role in filtration, I am sure that you would agree. I must say though, not thrilled with the Culligan Man reference.

Sean, what it means is that GAC is a good thing. It's truly beneficial to a filtration system, although maybe not necessary in many setups. Don't fear the carbon!

In Syracuse

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Post Options Post Options   Thanks (0) Thanks(0)   Quote jfinch Quote  Post ReplyReply Direct Link To This Post Posted: October 23 2003 at 9:28pm

Yes, adsorbtion is the reason I use it.  Oh you were getting at the longitivity issue... we may dissagree here .  Here's a past thread where we talked about this:  http://www.utahreefs.com/forum/forum_posts.asp?TID=1006.  Here's a quote from my post explaining my belief:

I think that when using the same bag of carbon for more then a week it's just working as substrate for bacteria.  The average pore size (diameter) is much much smaller then a single bacteria.  Once bacteria are established on the carbon surface they act like a "cover" over the surface keeping organic molecules from permeating into the active sites.  Therefore, when I use carbon I use a small amount and change it every week and when I do a water change.

I assumed the comments above were more directed at culinary water where bacteria growth is not an issue.  If it weren't for the bacteria, I think carbon could last very long indeed.  Some people suggest pulling the carbon bag out of the sump every week and "smashing" it against the counter top to break it up a bit and expose new surfaces to extend it's life.  I'm problably in the minority when it comes to this...

(not Culligan Man... how 'bout Kinetico Man )

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Post Options Post Options   Thanks (0) Thanks(0)   Quote jfinch Quote  Post ReplyReply Direct Link To This Post Posted: October 23 2003 at 9:44pm
Originally posted by jfinch jfinch wrote:

OCl-        +          C          =          CO2       +         Cl-
chlorine          Activated              Carbon           Chloride Ion
(as chlorate)    Carbon                Dioxide           (harmless)

  I seem to have messed up the equation (that's why I graduated in chemical engineering, not chemistry ).  Thanks Gonzo for seeing that!  I'm glad someone was actually looking at it...  It should be:

2 OCl-     +    C    =     CO2    +    2 Cl-



Edited by jfinch
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Post Options Post Options   Thanks (0) Thanks(0)   Quote Carl Quote  Post ReplyReply Direct Link To This Post Posted: October 24 2003 at 7:58am

JF, I guess that I will need to check into this a bit. True, pores will fill with organisms as easily as contaminants. However, there is a bit more to it than that I would believe. Not being a chemist, biologist or micro organism...ist...guy... I cannot offer an educated answer right now. Realistically, backflushing is key to extending the life of media. If this is done (by hose or other means), I would personally believe that the media's life is being cut too short. Additionally, using a prefilter that is cleaned periodically will help, let's say filtering to 1 to 5 micron nominal. Pressurizing through the media also helps.

But hey, if it works for you... Personally, I leave mine in for A LOT longer than you do... so far so good. Wanna test my water?

Let's talk about the petroleum industry again...    

In Syracuse

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Post Options Post Options   Thanks (0) Thanks(0)   Quote jfinch Quote  Post ReplyReply Direct Link To This Post Posted: October 24 2003 at 9:50am

How long do you leave it in for?  Do you use it passive (in a sock in the sump) or active (in a canister with pumped water passing through)?

Let's talk about the petroleum industry again...

Ya, what the h*ll does an oil man know about water anyway?  Let's change the topic... Anyone know what the "R+M/2" octane rating on the gas pump means?

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Post Options Post Options   Thanks (0) Thanks(0)   Quote Carl Quote  Post ReplyReply Direct Link To This Post Posted: October 24 2003 at 11:57am
Ryan...  ... and I am standing!
In Syracuse

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Post Options Post Options   Thanks (0) Thanks(0)   Quote jfinch Quote  Post ReplyReply Direct Link To This Post Posted: October 24 2003 at 2:16pm

Originally posted by rfoote rfoote wrote:

R+M/2

Smarta@@   

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Post Options Post Options   Thanks (0) Thanks(0)   Quote rfoote Quote  Post ReplyReply Direct Link To This Post Posted: October 24 2003 at 2:46pm
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