The newly mixed saltwater alters the surface tension (increases it) causing the skimmer to skim more for a short time. I usually switch my skimmer off for several hours after I do a water change for this reason.
Steve My Old 180G Mixed Reef Currently: 120G Wavefront Mixed 29G Seahorse & Softies Running ReefAngel Plus x2 435-8
I let my freshly-mixed SW sit overnight (with a circ pump and heater in the container) before doing a WC and that seems to alleviate the skimming issue
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